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Black Pepper Oil | Perfumery Raw Material
Black Pepper Oil | Perfumery Raw Material
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Black Pepper Oil
Black Pepper Oil is an essential oil obtained from black pepper with a warm, spicy-woody character – dominated by beta-caryophyllene, complemented by a facet-rich palette of natural terpenes.
Odor character
- Warm, spicy, woody-green, with a characteristic pungency
- Liquid, insoluble in water, soluble in ethanol
- Dominated by beta-caryophyllene (25–50%), complemented by limonene and other terpenes
Role in the formula
Black Pepper Oil brings a spicy-warm top-to-heart note into a composition and is frequently used in oriental, chypre-type or woody-spicy accords. The high content of beta-caryophyllene – the odor-defining main component of black pepper – gives the oil its characteristic, slightly pungent spice, while limonene and the accompanying monoterpenes provide additional freshness and complexity.
Use in perfumery
The manufacturer gives no specific dosage recommendation for this material in the available documentation. As with any new aroma material, it is advisable to start with small amounts in diluted form and increase gradually according to your own scent impression.
Practical note: dissolving, storing, combining
Dissolving: Practically insoluble in water, readily soluble in ethanol.
Storing: Store in tightly closed, preferably well-filled containers, cool, dry and well-ventilated, protected from light. Keep strictly away from ignition sources – the material is flammable.
Safety information
According to the current safety data sheet (version 4.0, 23 Jan 2023), Black Pepper Oil is classified under CLP Regulation (EC) No. 1272/2008 as: Flam. Liq. 3, H226 (flammable liquid and vapor), Skin Irrit. 2, H315 (causes skin irritation), Skin Sens. 1, H317 (may cause an allergic skin reaction), Asp. Tox. 1, H304 (may be fatal if swallowed and enters the airways), and Aquatic Chronic 2, H411 (toxic to aquatic life with long-lasting effects). Signal word: Danger.
Of particular note: in case of accidental swallowing, do not induce vomiting (aspiration hazard) – immediately contact a poison information center or a doctor. According to available test data, the product itself is considered non-eye-irritant (OECD 492) and non-mutagenic in the Ames test (OECD 471); acute oral toxicity is low (LD50 >5000 mg/kg, rat, OECD 401). The classification as skin-irritant and skin-sensitizing was derived from the properties of the individual components, as the product itself was not directly tested for these.
According to available data, the material is not readily biodegradable (72% biodegradation after 60 days, OECD 301F) and shows a certain bioaccumulation potential (log Kow 5.3). For alpha-pinene, beta-pinene and delta-3-carene, occupational exposure limits (VLA-ED) of 20 ppm or 113 mg/m³ respectively (8-hour average) apply in Spain. Protective gloves, protective clothing and eye protection are strongly recommended when handling the undiluted material. For transport: UN 1197 (extracts, liquid), Class 3, Packing Group III.
Physico-chemical properties
| Substance name | Black Pepper Oil |
| CAS no. | 84929-41-9 |
| EC no. | 284-524-7 |
| REACH registration number | 01-2120740133-68 |
| Physical state | Liquid |
| Boiling point | > 170 °C |
| Flash point | 46 °C |
| Density | 0.87–0.89 g/mL at 20 °C |
| Water solubility | Insoluble, soluble in ethanol |
| Main components | Beta-caryophyllene (25–50%), limonene (10–25%), plus beta-pinene, sabinene, alpha-pinene, delta-3-carene, beta-phellandrene, alpha-bisabolene (each 1–10%) |
FAQ
What is Black Pepper Oil?
An essential oil obtained from black pepper with a warm, spicy-woody character, dominated by beta-caryophyllene as the main component.
What is Black Pepper Oil typically used for?
As a spicy-warm top-to-heart note in oriental, chypre-type or woody-spicy compositions.
Is Black Pepper Oil classified as hazardous?
Yes. According to the current safety data sheet, the oil is classified as flammable, skin-irritant and skin-sensitizing, poses an aspiration hazard and is toxic to aquatic life. Signal word: Danger. Please read the safety information carefully before use – in particular: do not induce vomiting if swallowed.
Hazard Information (CLP Labelling)
Signal word: Danger
Hazard statements (H):
H226 – Flammable liquid and vapour.
H304 – May be fatal if swallowed and enters airways.
H315 – Causes skin irritation.
H317 – May cause an allergic skin reaction.
H411 – Toxic to aquatic life with long-lasting effects.
Precautionary statements (P):
P210 – Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P260 – Do not breathe mist/vapours.
P264 – Wash hands thoroughly after handling.
P272 – Contaminated work clothing should not be allowed out of the workplace.
P273 – Avoid release to the environment.
P280 – Wear protective gloves, protective clothing and eye protection.
P301+P310 – IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P331 – Do NOT induce vomiting.
P302+P352 – IF ON SKIN: Wash with plenty of water.
P308+P311 – IF exposed or concerned: Call a POISON CENTER/doctor.
P333+P313 – If skin irritation or rash occurs: Get medical advice/attention.
P391 – Collect spillage.
P403+P235 – Store in a well-ventilated place. Keep cool.
P501 – Dispose of contents/container in accordance with local regulations.
Substance: Black Pepper Oil (CAS 84929-41-9). The relevant CLP hazard-labelling elements (pictograms, signal word, H and P statements) pursuant to Regulation (EC) No 1272/2008 (CLP), as amended, are reproduced here in full. The legally binding labelling appears on the packaging.
Important note
This product is a perfumery raw material intended exclusively for fragrance development, creative experimentation, education and the study of perfumery materials. It is not a finished cosmetic product. Please observe the stated safety information particularly carefully – this material is flammable, poses an aspiration hazard and may cause allergic skin reactions.
